WebRead the passage given below and answer the following questions:According to Valence Bond Theory, the metal atom or ion under the influence of ligands can use its (n−1)d, ns, … WebMay 20, 2024 · Example \(\PageIndex{1}\): Colors of Complexes. The octahedral complex [Ti(H 2 O) 6] 3+ has a single d electron. To excite this electron from the ground state t 2g orbital to the e g orbital, this complex absorbs light from 450 to 600 nm. The maximum absorbance corresponds to Δ o and occurs at 499 nm. Calculate the value of Δ o in …
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Web3– d 6 16,800 13,000 high –0.4Δ o + P [Co(NH3)6] 3+ d 6 16,800 23,000 low –2.4Δ o +3P [Co(H2O)6] 2+ d 7 18,000 9,3000 high –0.8Δ o + 2P! Values of Δo depend on both the metal ion and the ligand.! Most aquo complexes are high spin, because H2O is a weak-field ligand.! Almost all Co3+ (d 6) complexes are low spin, including [Co(H2O)6 ... WebHomework help starts here! ASK AN EXPERT. Science Chemistry Though both [COF6]3 and [Co (CN)6]³- octahedral complexes, the crystal field stabilization energy (CFSE) of [COF6]3- complex is -0.4 kJ/mol whereas the CFSE of [Co (CN)6]³- complex is -2.4 kJ/mol. Draw the splitting pattern and explain this in detail. are. creative housing initiative program
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WebF − a `weak ligand The crystal field splitting will be small and hence maximum number of electrons will be unpaired (high spin complex). Co 3+ has 6 d electrons and in a weak … WebOption (B) is correct. In [CoF 6] 3−, cobalt has 3d 7,4s 2 system in ground state but in excited state it loses three electrons in the formation of ions and two elctrons from 4s and … WebConsider for example two complexes [Co(H2O)6]2+ and [Co(CN)6]4- [Co(H2O)6]2+ [Co(CN)6]4- Here in the above complexes we need to decide for which complex we need to add pairing energy along with CFSE will … creative housewares on line store